There's also http://csssprites.org/ (SmartSprites). The web based tools aren't really in the same category as Compass, Glue and SmartSprites - they can't be part of an automated build, so someone is going to have a repetitive manual task to do. Ok for a one-off, but annoying in the long term.
+1 for compass, but one problem with it is that (AFAIK) you can only do png sprites, so you can't do them for animated gif (for spinners and the likes).