"biggest" doesn't not mean most people support it. That's not how most democracies work - they have proportional representation, so they have many parties, and the biggest one may still only (as in this case) have a small percentage of the vote (in this case, 25%[0])
Defining extremists to be "the people with unpopular positions" is defining extremists to be "those with positions most dislike." AfD are extreme because of what their positions are, separate from who does and does not support them.
a cursory Google search reveals that they deny anthropogenic climate change, reject the idea of women in the workplace, and wish to deny marriage rights to homosexuals
They are conservative and have a few idiots and extremist people in their ranks yes, but that doesn't make the party as a whole extremist.
I never heard about their women-workspace-denial.
And being against marriage of homosexuals was the majority opinion from the beginning of time until around 10 years ago so you can hardly count that as extremist.
It is is supported by most, it is, by definition, not extremist. The word has a meaning, and it was not "something I happen to dislike"