For sheer shock value, little can beat the texting-while-driving one. No direct link but you can google "british texting while driving ad". The NZ safe driving ads are also really something. "new zealand safe driving shock ads" brings up one that really triggers, but then again, both the above particularly work if you're a parent.
The memorably stark tone and the frequency they were on TV made these spots ripe for parody, for example this one from Monkey Dust: https://www.youtube.com/watch?v=PsOk9Ln1qOY
Wow, that first one is genuinely horrific, I can’t believe they had the guts to release something so strong. Glad they did though, it probably saved a ton of lives.