I don't think so. With a police officer/arrestee relationship, coercive power is already being wielded. Being detained is inherently coercive. Any "request" from an officer acting in an official capacity is done with the implied backing of state power, and being arrested clearly establishes the coercive relationship.

But employment is transactional. There is an expectation that the agreed upon transaction will be upheld. A request that falls outside of the transaction, e.g. your boss asking you out, does not inherently imply economic coercion (whereas a request within the employment transaction does). But specifics of the context can alter that, i.e. wording of the request or specific context can imply coercion.